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The mechanism of bromine exchange in the bromine-graphite lamellar compounds

โœ Scribed by F.J. Salzano; S. Aronson


Book ID
118906027
Publisher
Elsevier Science
Year
1966
Weight
592 KB
Volume
28
Category
Article
ISSN
0022-1902

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Crystal structure of graphite bromine la
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The isotherm of bromine on pyrolytic graphite was studied at 20ยฐC by stepwise bromination, and several phases of graphite bromide were identified, which have compositions of C,Br, C,\*Br, C16Br and C,,,Br. X-ray studies show that these possess the socalled 2nd, 3rd, 4th and 5th stage structures resp

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rate of intercalation of graphite by bromine has been measured for natural crystals over a range of 500 fold in area and 10 fold in thickness. l'he results have been interpreted in terms of Fick's Law for radial diffusion in a cylinder and a mechanism in which all layers are open to intercalation as