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The mechanism of alkylation at C-24 during clionasterol biosynthesis in Monodus subterraneus

✍ Scribed by E.Ian Mercer; Wyn B. Harries


Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
401 KB
Volume
14
Category
Article
ISSN
0031-9422

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## Abstract The photorearrangement of cyclohex‐2‐enones 4a‐h to bicyclo[3.1.0]hexan‐2‐ones 5 and cyclopent‐2‐enones 6 (λ = 350 nm, MeCN) was investigated. Both the quantum yield (Φ~−4~ = 0.004– 0.024) and the product ratio (5/6 = 65:35–31:69) vary only over a rather small range, indicating the rear