𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The mechanical properties of short fiber-styrenic block copolymer composites

✍ Scribed by Michio Ashida; Wuyun Guo


Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
811 KB
Volume
49
Category
Article
ISSN
0021-8995

No coin nor oath required. For personal study only.

✦ Synopsis


The effect of fiber loading, fiber length, matrix type, and interface adhesion on mechanical properties of PET short fiber-styrenic block copolymer TPEs, SIS, and SBS, was investigated. A strong bonding between PET fiber and TPE was obtained by surface treatment of T P E with isocyanate in toluene solution. The stress of the composites, filled with treated fiber, increased with increasing strain by two steps; the modulus for the first step was higher than the one for the second step, and the composites yielded obviously at about 50% strain, with higher stress than that of matrix TPE. With increasing fiber loading and fiber length, the modulus for the first step and the yield stress increased, but the yield elongation decreased. It seems that the matrix elastomer underwent most of the deformation and that the filled fiber underwent large internal stress with little deformation during extension of the composite, which may be an important phenomenon to influence short fiber reinforcement. The stress softening of composites showed a somewhat larger decreased rate than that of the matrix with repeated stress-strain cycles, and the stress softening in the first cycle increased linearly with increasing fiber loading and increased in an S shape with increasing fiber length. In comparison with the SIS elastomer, the hysteresis of the SBS elastomer showed a big residual strain after the first elongation of 30%, and its retraction and subsequent re-extension curves were obviously different from the extension curve, which was considered to be due to the destruction of parts of the styrene hard domain in SBS. The stress softening of the composites was influenced by the matrix elastomer, as well as by the loading fiber. The interface separation around the end of a fiber under large strain, and the breaking and restructuring of hard domain in the matrix, were considered to be important sources of softening of the composite. 0 1993 John Wiley & Sons, Inc.


📜 SIMILAR VOLUMES


Conductivity and mechanical properties o
✍ Lucas G. Pedroni; Mauro A. Soto-Oviedo; J. Maurício Rosolen; Maria I. Felisberti 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 356 KB 👁 2 views

## Abstract Composites based on multiwall carbon nanotubes (MWCNTs) and the block copolymer styrene‐butadiene‐styrene with two different contents of styrene have been investigated and their electrical conductivity and mechanical properties have been evaluated. The composites were prepared by a solu

Mechanical properties of BIS-GMA resin s
✍ Krause, William R. ;Park, Sang-Hyun ;Straup, Robert A. 📂 Article 📅 1989 🏛 John Wiley and Sons 🌐 English ⚖ 719 KB

The use of short glass fibers as a filler for dental restorations or cement resins have not been examined extensively. The mechanical properties and untreated glass fibers (5 pm dia X 25 fim) in Bis-phenol A glycidyl methacrylate (BIS-GMA) diluted with triethylene-glycol dimethacrylate (TEGDMA) resi

Mechanical properties of styrene–butadie
✍ Xuefang Song; Hidetake Yoshino; Hiroshi Shibata; Asahiro Nagatani; Yasukiyo Ueda 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 459 KB 👁 2 views

## Abstract The factors influencing the mechanical properties of styrene–butadiene–styrene block copolymer (SBS) composites filled with liquid polybutadiene (LB)‐surface‐treated calcium carbonate (CaCO~3~) were investigated with respect to the molecular structure of the LB, the amount of the LB ads