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The mean bond dissociation energy of the carbonmagnesium bond in bis(2,2-dimethylpropyl)magnesium

✍ Scribed by O. S. Akkerman; G. Schat; E. A. I. M. Evers; F. Bickelhaupt


Book ID
104588489
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
487 KB
Volume
102
Category
Article
ISSN
0165-0513

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Guided ion-beam determination of the Co+
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A guided ion-beam tandem mass spectrometer with a flow tube ion source is used to determine the 0 K bond dissociation energy of Co+-H2 from ligand exchange of CoCH~ with D 2 and from collision-induced dissociation (CID) of CoH~ + Xe. Given Do(Co+-CH4 ) = 0.93 + 0.06 eV determined in our labs, the en