The mass spectrometric generation of neutral ethynamine HCCNH2 and other C2H3N isomers
✍ Scribed by John M. Buschek; John L. Holmes; F. P. Lossing
- Book ID
- 102558003
- Publisher
- John Wiley and Sons
- Year
- 1986
- Tongue
- English
- Weight
- 263 KB
- Volume
- 21
- Category
- Article
- ISSN
- 1076-5174
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Neutralization of a beam of vinylidene anions, [ CH,-C] -., by xenon gives rise to a stable CIHz species, having a lifetime 2 0.4 us. Re-ionization with oxygen generates a species which is identified byits collisional activation mass spectrum as the vinylidene radical cation, [CH+Z] +..
The CIHzNz isomers CH,\_N-CN and HN=CH-CN have been selectively generated, the former by flash vacuum pyrolysis of trimethylenetetrazole and SH, lOH-dihydroditetrazolo [ 15-a: 1',5'-d] pyrazine; the latter from azidoacetonitrile and from the lithium and sodium salts of the tosylhydrazone of I-cyanof
## Abstract The relative stabilities, isomerizations and dissociations of ionized dimethyl sulfoxide (DMSO), its three C~2~H~6~OS^+·^ isomers and of all their 14 conceivable CH~3~OS^+^ fragments (1–14), have been investigated by __ab initio__ calculations at the MP2/6–31G(d,p)//6–31G(d,p) + ZPE and