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The mass-spectral fragmentation of bicyclo[3.3.1]nonanes

✍ Scribed by R. Nicoletti; A. Gambacorta

Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
625 KB
Volume
7
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

The mass spectra of twelve bicyclo[3.3.1]nonanes have been recorded. The high number of metastables observed, exact mass measurements of the ions and low ionising voltage spectra, permitted the rationalisation of most of the fragmentation pathways. The 1‐phenyl substituent triggers the major fragmentation in the hydrocarbon, whereas it has minor influence in the oxygenated compounds. Significant differences in the abundance of [M ο£Ώ H~2~O]^+^ ions for stereoisomeric alcohols of this series have been observed.

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