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The mass spectra of some chlorinated aromatic pesticidal compounds

✍ Scribed by J. A. Sphon; J. N. Damico

Publisher
John Wiley and Sons
Year
1970
Tongue
English
Weight
542 KB
Volume
3
Category
Article
ISSN
1076-5174

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✦ Synopsis

Mass spectral studies of some chlorinated aromatic pesticidal compounds are reported. The compounds studied include substituted diphenyl derivatives of methane, ethene and methanol.

The diphenylmethanes are characterized by a relatively intense peak at m/e 165. Comparison of their low voltage spectra with 9-dichloromethylfluorene indicates that this ion has a fluorenyl ion structure.

The structure of the base peak (m/e 246) of the diphenylethenes was investigated by comparing competitive metastable transitions with 9-dichloromethylenefluorene and utilizing defocusing metastables. Additional studies of model compounds suggest that the m/e 246 ion is very complex and is

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