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The mass spectra of [17-13C]phyllocladene and [3-13C]methylenecholestane—III

✍ Scribed by R. A. Cruz; R. C. Castillo; F. J. Garcia; R. I. Reed

Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
243 KB
Volume
12
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

The mass spectra of [17‐^13^C]phyllocladene and [3‐^13^C]methylenecholestane have been examined. It is shown that there are some rearrangements at 70 e V as in the case of [17‐^13^C]kaurene. However, no extensive randomization is evident at the molecular ion level. The results are interesting because very little is known about ^13^C randomization in polycyclic aliphatic hydrocarbons. The percentage retention of label was calculated for each ion.

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