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The Marcus Inverted Region from Theory to Experiment

✍ Scribed by Priv.-Doz. Dr. Günter Grampp

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
327 KB
Volume
32
Category
Article
ISSN
0044-8249

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✦ Synopsis

Electron back‐transfer reactions are the reactions in which the occurrence of the inverted region predicted by the Marcus theory was detected for the first time in an __inter__molecular electron transfer. In this region, contrary to all intuition, a further increase in the exergonicity causes a decrease in the reaction rate. In each case the forward reactions showed the classical Rehm–Weller behavior the rate constant k approaches k~diff~ of the diffusion‐controlled reaction. This difference has not yet been explained satisfactorily.

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