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The Mannich Reaction with 1,2-Dibenzoylethane 1,2

โœ Scribed by Bailey, Philip S.; Lutz, Robert E.


Book ID
127114265
Publisher
American Chemical Society
Year
1948
Tongue
English
Weight
421 KB
Volume
70
Category
Article
ISSN
0002-7863

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Novel reactions producing 1,2-dibenzoyle
โœ Tamio Shirafuji; Yasusi Yamamoto; Hitosi Nozaki ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 127 KB

Few examples have been recorded with respect to the formation of 1,2-dibenzoylathanes II which involves dehalogenation condensation of phenacyl bromides I or recombination of phenaoyl radicals. Interestingly, treatment of Ia uith Ni(CO),, gives IIa in TRF, whereas the same components afford 2,4-diph