Accurate Born-Oppenheimer potential energy curves and adiabatic corrections are computed for the six lowest 1 u states of the hydrogen molecule. For the 4 1 u -6 1 u states adiabatic term values of the vibrational levels supported by the potentials and the corresponding rotational constants are give
The magnetizability of excited-state hydrogen: temperature-independent paramagnetism in the B1Σ+u state
✍ Scribed by Jacek Ryclewski; William T. Raynes
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 266 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
Reccwed 22 Dsccmber 19550 Components oi the mayxtlzabxhr> rensor for the B's: and n 3 $j states ot the hydrogen molecule have been calculated tar fired bond lengths nex eqbtllbrmm ft IS found thJt III the B 1X; s
📜 SIMILAR VOLUMES
Potetitial energy curYe for the excited B "YE+ state of the Ily&o~en mdlxulc WBS computed for intemuc1cv distances u 1.2 -G R -z 5.0 nu.-l-he dissocirtion-crgescv~uatedforH\*,HD aryd D~~csbovctheexperimen~resultsby 0.9.3.1xnd 27.2 qn-', respectively. The wavefunctionsobtained are employed to conputc
Supem~olecule calculations at the SCF level nre reported for the excited B 1 Xu state of the complex Hz(He)e for rqwlx and random&d environments of the hydrogen molecule. Whilst marked blue-shifts are observed in the simulated mnrris environmenf,mndomisation offhe surrounding h&urn atoms causes the
Cross scct~ons fix vrbrntional c-xltntlon (VE) of the X 1 Z: state of LQ wa formation of the cxnted A '$ or B II-I" eiectromc states are reported. For VE through the A ' ~6 state. the cross secttons are nearly constant for forming X ' ?I; (3 < U" < 9) WI electron colhslonnl cwltatlon. For photon pum