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The magnesium complexes of 1,2-dimethylenecycloalkanes: a new method for a one-step spiroannelation

✍ Scribed by Heping Xiong; Reuben D. Rieke

Book ID
104225293
Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
244 KB
Volume
32
Category
Article
ISSN
0040-4039

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✦ Synopsis

ReactIons of new dlenemagneszum reagents prepared from highly reactive magnesium and 1,2-dlmethylenecycloalkanes with l,n-dlbromoalkanes and bromoalkylnltrlles provide a one-step method

for the synthesis of commonly encountered spu-ocycllc systems.

Recently, we have shown that magnesium complexes of substituted 1,3-dlenes can be readily prepared using highly reactive magnesium.' These complexes function as bls-nucleophlles.

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## Abstract For Abstract see ChemInform Abstract in Full Text.