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The low temperature specific heat of κ-(BEDT-TTF)2Cu(NCS)2

✍ Scribed by R.G. Goodrich; Jing-chun Xu


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
304 KB
Volume
165-166
Category
Article
ISSN
0921-4526

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✦ Synopsis


We have measured the specific heat of lC-(BEDT-lTF>zCu(NCS>z from 4 to 14 K. The lattice specific heat is assumed to contain contributions due to 18 intra molecular coupled translational and libronic modes involving the two (BETF-TIP) molecules and the Cu(NCS)z, the phonon-libron contribution to the specific heat in our temperature range can be represented by a Debye integral expression with a Debye temperature of 95 K. This low value of the Debye temperature along with a T c of 9.4 K indicates a strong coupling superconductor if the electron -phonon and libron coupling is responsible for the pairing.


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An x-ray photoelectron spectroscopic (XPS) study of the 10.4K superconductor r-(BEDT-TrF)2Cu(NCS)2 is reported. Chemical environment of the atoms in this organic salt was discussed based on the XPS core-level results. Binding energies of the nonequivalent C and S sites in the donor BEDT-TTF and the