The low temperature magnetic susceptibility of Mn(HCO2)2.2H2O
β Scribed by A.Foner Cohen; S.A. Friedberg; G.R. Wagner
- Publisher
- Elsevier Science
- Year
- 1964
- Weight
- 152 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0031-9163
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The high-5eld EPR spectra of a mixed valence cluster compound of formula [Et 3 NH] 2 [Mn(CH 3 CN) 4 (H 2 O) 2 ] [Mn 10 O 4 (biphen) 4 Br 12 ] con5rm that the high-spin ground state (S β«Ψβ¬ 12) of the cluster has a negative zero-5eld splitting, D β«ΨΨβ¬ 0.037(1) cm Ψ1 . The reversal of the magnetization