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The low temperature gas phase oxidation of acetaldehyde and propionaldehyde

✍ Scribed by D.I. Bell; G. Skirrow; C.F.H. Tipper

Publisher
Elsevier Science
Year
1968
Tongue
English
Weight
196 KB
Volume
12
Category
Article
ISSN
0010-2180

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✦ Synopsis

An account is given of some observations of the low temperature oxidations of acetaldehyde and propionaldehyde in the gas phase with particular reference to the region in which the rates are oxygen dependent; these observations have formed the basis of a previous publication in which mechanistic features of the oxidations were examined by methods of numerical analysis. In addition, some unusual observations made during the oxidation of acetaldehyde ina pot~siumchloride coated vesselat temperaturc~ between 120'and 14fl~C are reported Withlhissurfacetherate is enhanced relative to that in a Pyrex vessel, and under certain conditions pressure pubes closely resembling those doe to cool flames are observed even at temperatures as low as 120"C.

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