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The low-frequency vibrations and the origin of hydrogen-bonded band profiles

โœ Scribed by D.N. Shchepkin

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
700 KB
Volume
156
Category
Article
ISSN
0022-2860

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Theory of profiles of hydrogen stretchin
Theory of profiles of hydrogen stretching infrared bands of hydrogen-bonded solids. Model of strong coupling between the high-frequency hydrogen stretching vibration and low-frequency phonons
โœ Henryk Ratajczak; Anatolij M. Yaremko ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 388 KB

A theory is developed to describe a broad IR absorption which appears in the range of a high-frequency stretching vibration of the X-H group involved in the hydrogen bond in solids. The theory is based on the anharmonic coupling mechanism between the high-frequency hydrogen stretching vibration, v(X