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The loss of a propyl radical from impact ionized 1-amino steroids

โœ Scribed by O. Lefevre; P. Longevialle


Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
247 KB
Volume
27
Category
Article
ISSN
1076-5174

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๐Ÿ“œ SIMILAR VOLUMES


Reactivity of electron impact ionized la
โœ O. Lefรจvre; N. Mollova; P. Longevialle ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 619 KB

Large-ring cycloalkylamines rearrange after electron impact ionization into long-chain enamioes. A general mechanism is proposed for their fragmentation, and a parallel is established with the fragmentation of long-chain esters (lipids). it is shown that the parent ions rearrange into a series of in

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## Abstract The electron impact mass spectra of 2โ€cyclohexenโ€1โ€ol and of several of its ^2^H and ^13^C labelled analogues show that the molecular ions lose a methyl radical by a completely different means from the mechanism described previously. Moreover, the retro Dielsโ€“Alder reaction also proceed