The loss of a propyl radical from impact ionized 1-amino steroids
โ Scribed by O. Lefevre; P. Longevialle
- Publisher
- John Wiley and Sons
- Year
- 1992
- Tongue
- English
- Weight
- 247 KB
- Volume
- 27
- Category
- Article
- ISSN
- 1076-5174
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Large-ring cycloalkylamines rearrange after electron impact ionization into long-chain enamioes. A general mechanism is proposed for their fragmentation, and a parallel is established with the fragmentation of long-chain esters (lipids). it is shown that the parent ions rearrange into a series of in
## Abstract The electron impact mass spectra of 2โcyclohexenโ1โol and of several of its ^2^H and ^13^C labelled analogues show that the molecular ions lose a methyl radical by a completely different means from the mechanism described previously. Moreover, the retro DielsโAlder reaction also proceed