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The London formula and the product vibrational state distributions of A + BC → AB + C chemical reactions

✍ Scribed by M. Shapiro; U. Halavee

Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 584 KB
Volume: 40
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(76)85101-9

No coin nor oath required. For personal study only.

✦ Synopsis

The vibrational product state distributions of a series of A + BC -, AB + C chemical reactions is expIained in terms of a simple analytic expression using parameters derived from a London-type formula. The importance of the energy barrier, Sato parameters in determining the vibrational state distributions of cxocrgic or endothermic chemical reactions is discussed. It is sugested that in many cases it is possible to make accumte predictions, regarding the outcome of a chemical reaction, solely on the basis of the spectroscopy of the separated reactants and products.

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