Intramolecular 2pπ* → 3dπ charge transfe
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Haruo Shizuka; Katsuhiko Okazaki; Masayuki Tanaka; Mitsuo Ishikawa; Minoru Sumit
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Article
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1985
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Elsevier Science
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English
⚖ 366 KB
In~mol~~ 2pn\* + 3dn charge transfer in the excited state of phenyl~e occurs very rapidly (<IO ps) both in ?&Fat 293 K and in EPA glass at 77 K. At room temperature a Iong;lived 425 nm transient (which is assgned to a reananged intermediate) is produced with a nse time of 30 ps, showing that the tra