The local field and charge-carrier mobilities in molecular crystals
β Scribed by R.W. Munn
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 334 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
Complete calculations of carrier mobilities in molecular crystals require the incaI electric field, related to the mrtcroscopic field vi:! the molccuiar polarizubility xxi crystal dieiectric tensors. Given rhe local field, off-diagonal mobility components car, be calcutatud from the di amx~sl ones. In anthrncene the local field is everywhere pnrailet to c the macroscopic field and some 67% larger.
π SIMILAR VOLUMES
A rigorous treatment of the local electric field is used to calculate effective molecular polarizabilitics from optical data for naphthalenc, anthracene, phenanthrene and biphenyl crystals. The principal axes of polarizability are typi-c~lly 10" from the molecular axes, in accord with spectroscopic