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The lithium perchlorate-diethyl ether rate acceleration of the Diels-Alder reaction: Lewis acid catalysis by lithium ion

✍ Scribed by Forman, Mark A.; Dailey, William P.

Book ID
120995360
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
290 KB
Volume
113
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

The cause of the rate acceleration by di
The cause of the rate acceleration by diethyl ether solutions of lithium perchlorate (LPDE) in organic reactions. Application to high pressure synthesis
✍ GΓ©rard Jenner; Ridha Ben Salem πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 536 KB

Kinetic ';tudies of isoprene c,,clodimenzation sh~ that the accelerating effect caused b 3 LPDE (soluti~m of lithium pcrchlorate in dieth~l ether) in some organic reactions canm~t be ascribed t~ internal pressure of LPDE. The kinetic effect is cssentiall 3 duc tt~ catal3sis through Li +. Addilional