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The Liquid−Glass and Liquid−Liquid Transitions of TPP at Elevated Pressure

✍ Scribed by Mierzwa, Michał; Paluch, Marian; Rzoska, Sylwester J.; Zioło, Jerzy

Book ID
124072214
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
851 KB
Volume
112
Category
Article
ISSN
0022-3654

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Slow dynamics at the liquid-glass transi
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✍ Hans-Otto Carmesin 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 301 KB

A fluid with isotropic particles is analyzed from first principles. Below the visco-elastic transition temperature, the relaxation time for the specific heat diverges according to a Vogel-F&her law. The reason for the discovered singularity is the volume excluded by a particle. So, the singularity i