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The liquid-phase oxidation of olefins by molecular oxygen in the presence of metal borides and MoO3

✍ Scribed by Yu. Trach; B. Schulze; O. Makota; L. Bulgakova

Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
95 KB
Volume
258
Category
Article
ISSN
1381-1169

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✦ Synopsis

The initial stages of the liquid-phase oxidation of 1-octene and cyclooctene by molecular oxygen in the presence of transition metal borides and MoO 3 are investigated. The investigated compounds influence the oxidation process only in the presence of hydroperoxide in the reaction system. The most active in this process is vanadium diboride. The molybdenum compounds activate the oxidation process of 1-octene and inhibit the oxidation of cyclooctene.

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