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The Lewis Acid Catalyzed Diels-Alder Reaction of 2-Diethylphosphoryloxy-1,3-Butadiene, an Oxygen-Substituted Diene of Unusual Stability

✍ Scribed by Liu, Hsing-Jang; Feng, Waiseng Martin


Book ID
120575241
Publisher
Taylor and Francis Group
Year
1987
Tongue
English
Weight
284 KB
Volume
17
Category
Article
ISSN
0039-7911

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Highly regioselective diels-alder reacti
✍ Akira Hosomi; Hirokazu Iguchi; Jun-ichi Sasaki; Hideki Sakurai πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 French βš– 232 KB

2-Trimethylsilylmethyl-1,3\_butadiene undergoes highly regioselective Diels-Alder reactions with dienophiles such as acrolein and methyl vinyl ketone catalyzed by aluminum chloride in which the "para" isomers are obtained almost exclusively. The adducts are converted readily to a variety of naturall