Nucleophilic substitution at a saturated
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Johann Gasteiger; Karlheinz Kaufmann; Christian Herzig; T.William Bentley
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Article
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1985
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Elsevier Science
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French
โ 195 KB
Whereas reaction of trans-2-chloro or 2-bromo-3-tert-butyloxirane with thiophenc Zate occuรฏ>s at C-3 to gi7>e 2-phenylmercapto-3,3-dimethyZbutanaZ,phenoZates give substitution at C-2 witk retention of tke oxirane ring and retention of configuration witk kinetics tkat indicate a bimoZecuZar meckanism