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The law of the reactions of trans-2-ethoxy-3,4-epoxyteteahydropyran with some nucleophiles containing a mobile hydrogen atom

โœ Scribed by V. B. Mochalin; A. N. Kornilov; B. V. Unkovskii


Book ID
112326366
Publisher
Springer US
Year
1973
Tongue
English
Weight
262 KB
Volume
9
Category
Article
ISSN
0009-3122

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Nucleophilic substitution at a saturated
โœ Johann Gasteiger; Karlheinz Kaufmann; Christian Herzig; T.William Bentley ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 195 KB

Whereas reaction of trans-2-chloro or 2-bromo-3-tert-butyloxirane with thiophenc Zate occuรฏ>s at C-3 to gi7>e 2-phenylmercapto-3,3-dimethyZbutanaZ,phenoZates give substitution at C-2 witk retention of tke oxirane ring and retention of configuration witk kinetics tkat indicate a bimoZecuZar meckanism