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The La2S3–LaS2 system: Thermodynamic and kinetic study

✍ Scribed by I.G. Vasilyeva; R.E. Nikolaev

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
194 KB
Volume
183
Category
Article
ISSN
0022-4596

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Rate constants, k, were determined for the solvolytic reactions of 2-bromo-2-methylbutane, 2-chloro-2methylbutane and 3-chloro-3-methylpentane in 10 pure diols at 298.15 K. The Gibbs energies of activation were calculated in order to study the influence of the solvent and to provide mechanistic info