The Kost—Sagitullin Rearrangement in a Series of 1-Alkyl-2-(carbamoylmethyl)-4,6-dimethylpyrimidinium Iodides.
✍ Scribed by G. G. Danagulyan; L. G. Sahakyan
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 17 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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Synthesis and Dimroth Rearrangement of 6-Cyano-1,2,4-triazolo[4,3a]pyrimidin-5-and 7-ones. A Novel Alkylation with Orthoesters and a New Participation of the Cyano Group in the Rearrangement. -Formic acid and triethyl orthoformate react with 2-hydrazinopyrimidin-4-ones (I) and (VI) to furnish triazo