✦ LIBER ✦

The kinetics of the solvolysis of chloropentacyanocobaltate(III) ions in water containing 2-methoxyethanol or diethylene glycol: A contrast with the effect of more hydrophobic cosolvents

✍ Scribed by Kamal H. Halawani; Cecil F. Wells

Publisher: Springer US
Year: 1994
Tongue: English
Weight: 596 KB
Volume: 23
Category: Article
ISSN: 0095-9782
DOI: 10.1007/bf00976258

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Kinetics of the solvolysis of chloropent

Kinetics of the solvolysis of chloropentacyanocobaltate(III) ions in water + 2-propanol mixtures

✍ Gehan M. A. El-Subruiti; Cecil F. Wells; Ibrahim M. Sidahmed 📂 Article 📅 1992 🏛 Springer US 🌐 English ⚖ 503 KB

Kinetics of the solvolysis of chloropent

Kinetics of the solvolysis of chloropentacyanocobaltate (III) ions in mixtures of ethane-1,2-diol or ethanonitrile with water

✍ Kamal H. Halawani; Cecil F. Wells 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 529 KB

The kinetics of the solvolysis of [Co(CN)&l13-ions have been investigated in mixtures formed by the addition of ethane-1,2-diol or ethanonitrile to water where the physical properties indicate little enhancement of structure in water-rich conditions. The effect on the kinetics of this solvolysis of

Kinetics of the solvolysis of chloropent

Kinetics of the solvolysis of chloropenta-amminecobalt(III) ions in mixtures of water witht-butyl alcohol or with 2-methoxyethanol

✍ Kamal H. Halawani; Cecil F. Wells 📂 Article 📅 1994 🏛 Springer 🌐 English ⚖ 516 KB

As the transition state for the solvolysis of [Co(NH3)sC1] z + ions is known to have C1 ions in a situation closely similar to that in the bulk solvent, the kinetics of this solvolysis have been investigated for comparison in H20 with added cosolvents of low and high hydrophobicities. A linear varia

Kinetics of solvolysis of trans-dichloro

Kinetics of solvolysis of trans-dichlorotetra (t-butylpyridine)-cobalt(III) ions in mixtures of water with ethane-1,2-diol and with 2-methoxyethanol. A contrast with the effect of hydrophobic co-solvents

✍ Kamal H. Halawani; Cecil F. Wells 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 545 KB

The kinetics of the solvolysis of the hydrophobic ion, Co(4-t-Bupy)dCl:, have been followed in mixtures of water with co-solvents having a hydrophilic tendency, ethane-1,2-diol and 2-methoxyethanol. The variation of ln(rate constant) with the reciprocal of the dielectric constant is nonlinear for bo