16 h gives the 4,5,6-trinitro ketone (2), labelled (15N02) at C6 but not at C4, and recovered 4-nitrodienone (1) in which extensive loss of 15N02 has occurred. The mechanistic implications of these and related results are discussed. Reaction Of 2,6-di-t-butyl-4-methylphenol (3) with excess nitrogen
The kinetics of the reactions of 2,6-di-t-butyl-4-methylphenol and 2,4,6-trimethylphenol with nitrogen dioxide in solution
โ Scribed by Robert G. Coombes; Andrew W. Diggle; Stewart P. Kempsell
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 208 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
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## Abstract Convenient procedures for the synthesis of functionalized monoโ and bisphosphinates with 2,6โdiโtertโbutylโ4โmethylphenol (ionol) fragments, starting from the available 3,5โdiโtertโbutylโ4โbenzaldehyde and its derivatives, are proposed, and some properties of the new phosphorusโsubstitu
Radical pairs are formed by photolysis of single crystals of 2,6-di-tert-butyl-4-methylphenol (ionol) (1) or 2,6-di-tert-butylphenol (2 ), doped by several different molecules, and investigated by the EPR method. A possible two-hydrogen-atom transfer is discussed as the photochemical act.