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The Kinetics of the Reaction of Methanol with 3,3'-Dicarbazylphenylmethyl Ion in Alkaline Solution

โœ Scribed by Branch, Gerald E. K.; Tolbert, B. M.


Book ID
126009032
Publisher
American Chemical Society
Year
1947
Tongue
English
Weight
777 KB
Volume
69
Category
Article
ISSN
0002-7863

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The kinetics of the reaction of 2-chloro-3-nitropyridine (ortho-like) and 2-chloro-5-nitropyridine (para-like) with a series of aryloxide ions were studied in methanol at different temperatures. Plots of DH โ‰  versus DS โ‰  for both reactions gave good straight lines with isokinetic temperatures of 168