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The kinetics of the reaction of iodine with hydrazine as studied by pulse radiolysis

✍ Scribed by I. Janovský


Book ID
112707864
Publisher
Springer
Year
1986
Tongue
English
Weight
466 KB
Volume
103
Category
Article
ISSN
1588-2780

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✍ Jerzy T. Jodkowski; Emil Ratajczak; Alfred Sillesen; Palle Pagsberg 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 584 KB

The reaction CHs+NO (+M) +CH,NO (+M) was initiated by pulse radiolysis of acetone/nitric oxide mixtures and the kinetics of methyl radicals was studied by time-resolved infrared absorption spectroscopy. The rate constant was found to be strongly pressure dependent in the range of p( M ) =6.5-150 mba