✦ LIBER ✦

The kinetics of the reaction between NH2 and propylene studied by laser resonance absorption

✍ Scribed by R. Lesclaux; J.C. Soulignac; Pham Van Khě

Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 355 KB
Volume: 43
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(76)80614-8

No coin nor oath required. For personal study only.

✦ Synopsis

The roatlon kmctics of NH* with propylcnc is studied by ilab pbotolysis in tbc temperature range 300-500 K. The Nil* radicals drc dctcctcd by re$ondncc absorption, using B cw sin& mode dyu laser. This method allows the dctcction of very ~lall radxal concentrations in a wide rnrqe of cxper!mcntal conditions. Tbc rcnction of NIIZ with propylcnc is fairly slow and scum: to correspond to tbc ad&ion process. The Arrbenius cxprcssion obtamcd ir (I? in kcnl/mole): k(NIIz + C311d -2.9 x lo8 cxp[-4.3(* 0.2)/HT] hl-'s-r.

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