The Kinetics of the NO-N 2 O 5 Reaction 1
β Scribed by Hisatsune, I. C.; Crawford, Bryce; Ogg, R. A.
- Book ID
- 125943538
- Publisher
- American Chemical Society
- Year
- 1957
- Tongue
- English
- Weight
- 484 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The gas-phase reaction of the NOa radical with NO, was investigated, using a flash photolysis-visible absorption technique, over the total pressure range 25-400 Torr of nitrogen or oxygen diluent a t 298 2 2 K. The absolute rate constants determined (in units of em3 molecule-' s-') a t 25, 100, and
The equilibrium constant, K,, of the reaction NO2 + NO3 + M N z O ~ + M has been determined for a small range of temperatures around room temperature in air at 740 torr by direct spectroscopical measurements of NOz, NOS, and NzOs. At 298 K, K, was determined as (3.73 2 0.61) x lo-'' cm3 molecule-'.