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The kinetics of the formation of stable nitroxyl radicals in the oxidation of sterically hindered amines by singlet oxygen in a solid polymeric matrix

✍ Scribed by O. M. Anisimova; V. B. Invanov; V. M. Anisimov; A. B. Shapiro; É. G. Rozantsev


Book ID
112441903
Publisher
Springer
Year
1978
Tongue
English
Weight
457 KB
Volume
27
Category
Article
ISSN
1573-9171

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Theoretical study of a silylene-oxygen a
✍ Shigeru Nagase; Takako Kudo; Takeshi Akasaka; Wataru Ando 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 539 KB

In an attempt to reinforce our recent experiments on silylene-oxygen adducts, the structure and kinetic stability of silanone oxide (H2SiOO) in the singlet state have been investigated at several levels of theory. It is found that &none oxide has a nonplanar, pyramidal structure and undergoes rapid