The anti-dithietane-1,3-dioxide β syn-dithietane-1,3-dioxide isomerization reaction has been theoretically studied on the frame of MO theory both in the gas phase and in solution. In the gas phase the anti (II a ) } syn (II s ) equilibrium is slightly displaced to the anti isomer formation. The syn
The kinetics of syn-anti interconversions in arylidene semicarbazones
β Scribed by F.L. Scott; T.M. Lambe; R.N. Butler
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 173 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Reaction of arylidene semicarbasones (I) with bromine in aqueous acetic acid leads to the oxadiazoles (II) (Scheme 1). Despite the clear intervention of bromine in this process we have found that rate-N -N Ii
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