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The Kinetics of Solvolysis of Acyl Esters of Salicyclic Acid

✍ Scribed by Garrett, Edward R.


Book ID
125849652
Publisher
American Chemical Society
Year
1957
Tongue
English
Weight
817 KB
Volume
79
Category
Article
ISSN
0002-7863

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Structure dependence in the solvolysis k
✍ John Haseltine; Jason W. Runyon πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 French βš– 190 KB

To better understand acyl transfer reactions of oligopeptides, seventeen N-acyl amino acid esters were solvolyzed in mildly basic methanol-d 4 . All show pseudo-first-order kinetics by 1 H NMR. The rate constant varies up to 400-fold with the identity of the amino acid and up to 6200-fold with the i