The kinetics of reaction between permanganate and chlorine ions in acid solutions
β Scribed by A. V. Levanov; I. V. Kuskov; E. E. Antipenko; V. V. Lunin
- Book ID
- 110183269
- Publisher
- International Academic Publishing Co (Nauka/Interperiodica)
- Year
- 2006
- Tongue
- English
- Weight
- 160 KB
- Volume
- 80
- Category
- Article
- ISSN
- 0036-0244
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## Abstract For Abstract see ChemInform Abstract in Full Text.
The measurements of the rate of absorption of CO, into aqueous solutions of KOH, NaOH and LiOH containing neutral electrolytes (carbonates, chlorides, bromides, nitrates and sulphates) have been performed using the laminar-jet technique. The dependence of the reaction rate constant on the temperatur
The kinetics of the permanganate oxidation of formic acid in aqueous perchloric acid a t 30Β°C were examined by the spectrophotometric method. The chemical reaction 2Mn0, A BHCOOH + 2H + -2Mn02 + 3C0, + 4H20. appears to proceed via several parallel reactions. The overall rate equation has been obtain
The reaction has been studied spectrophotometrically monitoring the absorbance in the wavelength range. The spectra of the reactants, intermediates, and prod-240-400 nm ucts in this system are overlapping; thus special programs [1,2] have been used (and tested) to unravel the kinetics and mechanism