The kinetics of polymerization of vinyl acetate in methanol
β Scribed by L. Alexandru; M. Oprish
- Book ID
- 118355611
- Publisher
- Elsevier Science
- Year
- 1962
- Weight
- 192 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0032-3950
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Transport of free radicals out of latex particles into the aqueous phase plays an important role in the emulsion polymerization of vinyl acetate. This so-called "desorption" process involves chain transfer to monomer which generates a mobile an8 rather stable monomer-unit free radical followed by th
## Abstract The kinetics of vinyl chloride and vinyl acetate emulsion polymerization are reexamined. The validity of Ugelstad's model for systems with high desorption rate is confirmed by simulating conversion histories for both systems at different initiator concentrations and particle numbers. On