The kinetics of electron-transfer reactions of the [FeCp(CpCH2N(CH3)3]+/2+ couple in the presence of cyclodextrins in aqueous media
โ Scribed by Jerome A. Imonigie; Donal H. Macartney
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 669 KB
- Volume
- 225
- Category
- Article
- ISSN
- 0020-1693
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract The gas phase reaction kinetics of OH with three diโamine rocket fuelsโN~2~H~4~, CH~3~NHNH~2~, and (CH~3~)~2~NNH~2~โwas studied in a discharge flow tube apparatus and a pulsed photolysis reactor under pseudoโfirstโorder conditions in [OH]. Direct laserโinduced fluorescence monitoring of
A study of the reaction initiated by the thermal decomposition of di-t-butyl peroxide (DTBP) in the presence of (CHa)?C=CHz (B) at 391-444 K has yielded kinetic data on a number of reactions involving CH3 (M.), (CH&CCHzCH3 (MB.) and ( C H ~) ~C C H ~C ( C H ~) Z C H ~C H ~ (MBB.) radicals. The cross
Energy transfer processes between metastable atoms He(2 'S) and CHaCI, have been investigated by emission spectroscopy. Intense CH(,4+X), CH(B+X), CH(C+X) and CCI(A+X) emission bands and weak hydrogen Balmer lines were observed. Using the reference reaction He(2 'S)+CO, the formation rate constant o
The effect of electron correlation on the energy profile of an SR2 gas-phase reaction is studied within Brauman's double-well model. Correlation ~n~~utions to the well depth, intrinsic and overall bar&Is and the heat of reaction are ~lc~~d using complete fourth-order MBPT. It is shown that electron