The Kinetics and Rapid Thermochemistry of Carbonic Acid
β Scribed by Roughton, F. J. W.
- Book ID
- 125974090
- Publisher
- American Chemical Society
- Year
- 1941
- Tongue
- English
- Weight
- 482 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Data on the kinetics of S,F,, pyrolysis, which gives SF, + SF, , have been reinterpreted to give a value for the equilibrium constant of S,FIo SF, + SF, . This, together with statistical estimates of the entropy and heat capacity of S,F,, , can be used to give for this reaction values of AH,.,, = 19
Laser flash photolysis of C1,/Oz mixtures has been employed in conjunction with Cl( 2P,,2) detection by time-resolved resonance fluorescence spectroscopy to investigate equilibration kinetics for the reactions C1+Oz +O,:ClOO+O, at temperatures of I8 I-200 K and O2 pressures of 15-40 Torr. The third-