The homogeneous gas-phase decomposition kinetics of silane has been investigated using the single-pulse shock tube comparative rate technique (T = 1035-1184Β°K, P ~d = 4000 Torr). The initial reaction of the decomposition SiH4 ! + SiHz + H2 is a unimolecular process in its pressure fall-off regime w
The kinetics and mechanism of ultracentrifugal demulsification
β Scribed by Alice Ulhee Hahn; Robert D Vold
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 606 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0021-9797
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π SIMILAR VOLUMES
The homogeneous gas-phase thermal decomposition kinetics of germane have been measured in a single-pulse shock tube between 950 and 1060 K at pressures around 4000 torr. The initial decomposition is GeH4 -GeH2 + H2 in its pressure-dependent regime, with log k ~~~~( 4 m ) = 13.83 f 0.78 -50,750 f 357
The kinetics of the hydrolysis of imidacloprid were studied at diΓΎ erent pH values and under various temperatures. Imidacloprid was found to be stable in acidic and neutral water, but readily hydrolysed in alkaline water. The main hydrolysis product was found to be 1-[ (6-chloro-3pyridinyl)methyl ]
## Abstract The rate of the inhibited pyrolysis of pentachloroethane was studiedover the temperature range of 820 to 865Β°K using the tolueneβcarrier technique in a stirredβflow reactor. The pyrolysis rate was found to be first order in reactant, and the rate constant is described by __k__=10^11.6Β±0
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