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The kinetics and mechanism of the oxidation of DL ethionine and thiourea by potassium ferrate

โœ Scribed by John F. Read; K. Julia MacCormick; Adina M. McBain

Book ID
111613532
Publisher
Springer
Year
2004
Tongue
English
Weight
143 KB
Volume
29
Category
Article
ISSN
0340-4285

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Kinetics and mechanism of the oxidation
Kinetics and mechanism of the oxidation of thiourea by chlorine dioxide
โœ Gyula Rรกbai; Robert T. Wang; Kenneth Kustin ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 602 KB

The stoichiometry and kinetics of the oxidation of thiourea (SC(NH2)z) by chlorine dioxide (ClOz) have been studied by uv-vis spectrophotometry using conventional and stopped-flow mixing techniques at 25.0 ? O.l"C, pH 0.3-4.8. In high acid and initial 10 : 1 molar ratio of thiourea to chlorine dioxi