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The kinetics and mechanism of diene exchange in (η4-enone) Fe(CO)2L complexes (L = phosphine, phosphite)

✍ Scribed by James A.S. Howell; John C. Kola; Denis T. Dixon; Philip M. Burkinshaw; Marion J. Thomas


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
788 KB
Volume
266
Category
Article
ISSN
0022-328X

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For the first time, 2D(3'P, s7Fe){1H}-triple-resonance NMR spectroscopy was used at low temperatures (213 and 179 K) to study the conformers of (q4-benzylideneacetone)-and (q4-diene)Feo(CO),L complexes (L = phosphanes, phosphites). In some cases not only the 57Fe chemical shifts and the 1J(57Fe, 31P