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The kinetics and energetics of formation of a molecular hydrogen complex involving a dinuclear ruthenium(II) centre

✍ Scribed by Daniel E.K.-Y. Chau; Brian R. James


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
622 KB
Volume
240
Category
Article
ISSN
0020-1693

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The rate constant of formation, dissociation, and redox reaction of the benzyl radicalcopper(I1) ion complex have been determined at temperatures from 274 K to 333 K by laser flash photolysis of 1,3-diphenyl-2-propanone (DBK) in a 10% acetonitrile-90% water mixture containing copper(I1)perchlorate.