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The kinetic theory of thermal hysteresis of a macromolecule solution

✍ Scribed by Qianzhong Li; Liaofu Luo

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
348 KB
Volume
216
Category
Article
ISSN
0009-2614

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✦ Synopsis

By use of the Flory-Huggin lattice model, the kinetic theory of the thermal hysteresis (the difference between the growing point and melting point of ice crystals) of a macromolecule solution is presented. As an example, the thermal hysteresis of an antifreeze protein solution is calculated.

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## Abstract We propose an analytical approach to calculate the effective dielectric function of proteins in aqueous solution. The screening effect if quantified by a measure of enclosure which is based on the distribution of solute atomic volumes around a pair of charges in a macromolecule. For pro