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The kinetic equations for isotopic exchange reactions allowing for the presence of an isotope effect

✍ Scribed by Logan, S. R. ;Shannon, G. P.


Book ID
112686088
Publisher
Springer
Year
1994
Tongue
English
Weight
271 KB
Volume
53
Category
Article
ISSN
0133-1736

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## Abstract Multistep hydrogen isotope exchange reactions, such as the Γ­onization of a carbon acid via a carbanion intermediate in a protic solvent, when conducted using an isotopic tracer to monitor the exchange, have the unusual feature that their rate‐determining steps always refer to the transf