The Kinetic Acidity of Oligofluorobenzenes Correlated with Their Gas Phase Deprotonation Energies

Gas-phase elimination kinetics of ethyl,

Gas-phase elimination kinetics of ethyl, isopropyl and tert-butyl N,N-diethylcarbamates. application of taft–topsom correlation for substituents other than carbon at the acid side of organic ethyl esters

✍ Armando Herize; Rosa M. Dominguez; Alexandra Rotinov; Oswaldo Nuñez; Gabriel Chu 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 63 KB 👁 2 views

The elimination kinetics of ethyl, isopropyl and tert-butyl N,N-diethylcarbamates were investigated in a static reaction vessel over the temperature range 220-400 °C and pressure range 17-160 Torr. These reactions are homogeneous, unimolecular and follow a first-order rate law. The temperature depen