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The Key Role of the Intermolecular π−π Interactions in the Presence of Spin Crossover in Neutral [Fe(abpt) 2 A 2 ] Complexes (A = Terminal Monoanion N Ligand)

✍ Scribed by Dupouy, Gaelle; Marchivie, Mathieu; Triki, Smail; Sala-Pala, Jean; Salaün, Jean-Yves; Gómez-García, Carlos J.; Guionneau, Philippe


Book ID
125899555
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
794 KB
Volume
47
Category
Article
ISSN
0020-1669

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Mulliken n.aσ and bπ.aσ complexes B…Cl2
✍ A.C. Legon 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 465 KB

Comparison of the angular geometries of a series of B... C12 complexes of the Mulliken n.a~r and b~r.atr type with those of the series B...HCI, where B = CO, HF, PH 3, H2S, C2H2, C2H 4 HCN, and NH3, reveals the two series to be isostructural for a given B. Rules for predicting the angular geometries