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The Kagomé Topology of the Gallium and Indium Metal-Organic Framework Types with a MIL-68 Structure: Synthesis, XRD, Solid-State NMR Characterizations, and Hydrogen Adsorption

✍ Scribed by Volkringer, Christophe; Meddouri, Mohamed; Loiseau, Thierry; Guillou, Nathalie; Marrot, Jérôme; Férey, Gérard; Haouas, Mohamed; Taulelle, Francis; Audebrand, Nathalie; Latroche, Michel

Book ID
120060766
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
447 KB
Volume
47
Category
Article
ISSN
0020-1669

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The Kagomé Topology of the Gallium and
The Kagomé Topology of the Gallium and Indium Metal-Organic Framework Types with a MIL-68 Structure: Synthesis, XRD, Solid-State NMR Characterizations, and Hydrogen Adsorption
✍ Volkringer, Christophe; Meddouri, Mohamed; Loiseau, Thierry; Guillou, Nathalie; 📂 Article 📅 2008 🏛 American Chemical Society 🌐 English ⚖ 447 KB

The vanadium-based terephthalate analogs of MIL-68 have been obtained with gallium and indium (network composition: M(OH)(O 2 C-C 6 H 4 -CO 2 ), M ) Ga or In) by using a solvothermal synthesis technique using N,Ndimethylformamide as a solvent (10 and 48 h, for Ga and In, respectively, at 100 °C). Th