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The isomorphous transition between Co(NH3)6(PF6)2and Ni(NH3)6(PF6)2

✍ Scribed by G.J. Kearley; P. Schiebel; M. Johnson; E. Bruck

Publisher
Springer
Year
2002
Tongue
English
Weight
92 KB
Volume
74
Category
Article
ISSN
1432-0630

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Electric permittivity e\*= e'-ie" of nickel-hexammino nitrate (NHN) has been measured within the range of temperature from 9 to 300 K at a frequency of 8.8 GHz (X-band). It has been found that the phase transitions at Tkl =247K and Tk2 =90K are discontinuous structural transitions between centrosymm